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Rutile Anatase Mixed

Band alignment of rutile and anatase TiO2

2013年7月7日  Nature Materials - A convincing explanation of why mixed phases of anatase and rutile TiO2 outperform individual polymorphs is

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Rutile and anatase mixed crystal TiO - ScienceDirect

2006年12月5日  The crystal structures of the mixed crystal were analyzed as being rutile or anatase by the X-ray diffraction (XRD) method. We explain the growth of the mixed

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Synthesis of anatase and rutile mixed phase titanium dioxide ...

2022年8月1日  In this present study, anatase and rutile mixed phase TiO 2 nanoparticles have been prepared by an eco-friendly simple solution combustion method in a single

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Interface junction at anatase/rutile in mixed-phase TiO

2011年2月28日  Nanosized TiO 2 photocatalysts of anatase, rutile and mixed-phase were synthesized through hydrolysis method. The influence of the interface junction between

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Preparation and Photocatalytic Performance of Anatase/Rutile Mixed ...

2010年8月13日  Herein we report a novel method to synthesize anatase-dominated anatase/rutile mixed-phase TiO 2 nanotubes via liquid phase deposition and subsequent

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Review of the anatase to rutile phase transformation

2010年12月8日  Anatase transforms irreversibly to rutile at elevated temperatures. This transformation does not have a unique temperature and the processes that are involved

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Band Alignment and Controllable Electron Migration between Rutile

2015年7月14日  The highly photocatalytic active form is its mixed phase of two polymorphs anatase and rutile rather than their pristine compositions. Such a synergetic effect is

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Quantum dynamics origin of high photocatalytic activity of mixed

2020年7月27日  Mixed anatase/rutile TiO 2 exhibits high photocatalytic activity; however, the mechanism underlying the high performance of the mixed phases is not fully

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Efficient Photocatalytic Nanocomposites of Anatase/Rutile Mixed

2022年8月5日  The XRD-based structural examinations determined the occurrence of anatase/rutile mixed phases of titania in all nanocatalysts alongside the MWCNTs and

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Characteristics and performance of rutile/anatase/brookite

Characteristics and performance of rutile/anatase/brookite TiO2 and TiO2–Ti2O3(H2O)2(C2O4)H2O multiphase mixed crystal for the catalytic degradation of

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Hydrothermal synthesis of a rutile/anatase TiO2 mixed

Nowadays, rutile TiO 2 or anatase TiO 2 is prepared from titanium oxalate, but there are only few studies on the rutile/anatase TiO 2 mixed crystal. In this study, using potassium titanyl oxalate as the titanium source, titanium oxalate [Ti 2 O 3 (H 2 O) 2 (C 2 O 4)H 2 O] has been prepared by a one-step hydrothermal method at 120 °C. When the temperature

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Effect of Ag doping on phase-change and photocatalytic

2022年8月12日  conrmed the rutile–anatase mixed-phase TiO 2 photocatalysts. The role of Ag doping was also investigated in the phase transformation of mixed-phase TiO 2 nanoparticles. Further, the eect of mixed-phase and Ag doping on photocatalytic activity was also investigated. The pure and Ag-doped TiO 2 photocatalysts were monitored for

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Phase evolution, morphological, optical and

2020年6月23日  A mixed-phase (anatase/rutile) TiO2 thin film was produced at a substrate temperature of 400 °C when samples are fabricated with anatase and rutile target materials. The results of this study ...

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Enhanced visible-light photocatalytic activity of anatase

2020年1月13日  of rutile and anatase phases, respectively. It was also shown that the transformation from anatase to rutile induced by high-temperature heat treatment was almost completed at 750°C, whereas a small amount (less than 3 mass%) of anatase phase was still left even in the powder heat-treated at 900°C. The

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Wetting Properties of Transparent Anatase/Rutile Mixed

2020年6月8日  Depending on the glancing angle and the pressure, rutile, mixed anatase/ rutile and pure anatase were deposited at low substrate temperature. Both hydrophilic and hydrophobic TiO2 were obtained, exhibiting fast photoconversion to superhydrophilic upon UV irradiation. The effect of the materials physicochemical properties on the wettability

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Carbon-regulated titania crystallization to construct a

Capitalized on the concentration-regulated balance between the promotive and inhibitory effects of carbon doping on titania crystallization, we unveiled two structural criteria of the anatase phase – crystal size of about 14 nm and crystallinity of about 30% – for ART but also devised 125 titania samples of defined but varied anatase/rutile ...

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Self-induced synthesis of phase-junction TiO2 with a tailored rutile

2016年2月11日  Rutile/anatase-mixed TiO 2 nanocomposites were prepared as follows: the as-prepared purple solution was annealed at different temperatures (300, 350, 400, 450, 500, 600, 700 and 800 °C (denoted ...

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High-temperature solid-state rutile-to-anatase phase

2022年11月1日  Anatase TiO 2 (A-TiO 2) was obtained by annealing the synthesized rutile TiO 2 powder in a two-step thermal process under NH 3 flow and subsequently in air. R–TiO 2 was first heated under an NH 3 atmosphere to replace some of the oxygen atoms in the rutile lattice with N atoms. This process produced dramatic changes in the crystalline

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Synthesis of anatase and rutile mixed phase titanium dioxide ...

2022年8月1日  The HR-TEM images of TiO 2 nanoparticles were shown in Fig. 4 a2, 4b2 and 4c2, confirming the mixed anatase and rutile phases with the appropriate d spacing values. Analysis of the lattice fringes of individual small crystallites in the high-resolution image confirms the presence of anatase and rutile mixed phases. The lattice spacing

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Structural characterization of N-doped anatase–rutile mixed

2015年1月23日  Abstract In this study, N-doped anatase–rutile mixed phase TiO2 nanorods assembled microspheres were synthesized via a direct and simple sol–gel method. The physical analysis via X-ray diffraction indicated that the prepared sample had a mixed phase of anatase and rutile TiO2. The morphology of the structure was observed with field

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Controllable One-Step Synthesis of Mixed-Phase TiO

2021年5月20日  In this study, the novel mixed-phase TiO2 nanocrystals (s-TiO2) with nearly equivalent anatase/rutile ratio were fabricated in the reagent of sec-butanol at the relatively low temperature of 80 °C by using

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Understanding the surface reduction of nano rutile and anatase ...

2020年1月1日  TiO 2 possesses various phases including rutile, anatase, brookite, and TiO 2-B, among which rutile and anatase are the most widely investigated ones. ... Then, TiO 2 nanoparticles were uniformly mixed with Mg metal powders in different molar ratios prior to being sealed in a quartz tube and calcined at 450 °C for 10 h.

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Pulsed-laser deposition and photocatalytic activity of pure rutile

2022年8月1日  1. Introduction. Titanium dioxide (TiO 2), also known as titania, is an extremely versatile wide-band-gap semiconductor existing in three crystalline phases, anatase (tetragonal), rutile (tetragonal) and brookite (orthorhombic) with different properties and thermodynamic stability.. At the bulk scale, rutile represents the most stable high

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Synthesis, structural and electrical properties of PVA/TiO2 ...

2020年9月9日  Different phases (rutile, anatase, and mix between them) of TiO 2 were successfully synthesized by the sol–gel technique. The controlling of calcination temperature is the key to the nanoparticle phase change. It starts from the anatase phase at 250 °C and ends by the rutile at 850 °C passing by the mixed-phase at 500 °C.

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Band Alignment and Controllable Electron Migration between Rutile

2015年7月14日  The inconsistency for the experimentally determined band alignment of the mixed-phase TiO 2 can mainly be attributed to the lack of the model TiO 2 systems with well-defined anatase/rutile ...

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Quantum dynamics origin of high photocatalytic activity of mixed

2020年7月27日  Mixed anatase/rutile TiO 2 exhibits high photocatalytic activity; however, the mechanism underlying the high performance of the mixed phases is not fully understood. We have performed time-domain ab initio calculations to study the exited state dynamics in mixed phase TiO 2 and to investigate the impact of an oxygen vacancy on the dynamics.

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Low-temperature chemical synthesis of rutile and anatase mixed

2017年5月15日  Wet chemical deposition method by using copper salt doping approach is used to synthesize mixed phase (rutile and anatase) titanium dioxide (TiO 2) nanostructures.Pristine and Cu-doped TiO 2 photoanodes are analyzed for their physical properties. The results showed a significant influence of Cu-salt concentration in tuning

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Enhanced visible-light photocatalytic activity of anatase-rutile mixed ...

2020年1月15日  Optimum rutile/anatase ratio in mixed-phase TiO 2 for the photocatalytic performance cannot be determined unambiguously. In this work, photocatalytic performance was enhanced to reach an optimum heating temperature, approximately 800°C, and deteriorated by higher-temperature heat treatment.

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Explaining the High Photocatalytic Activity of a Mixed Phase

2011年9月20日  The synergistic effect between anatase and rutile TiO 2 particles for organic photodegradation in an aerated aqueous suspension has been widely reported, ascribed to the charge transfer between two oxides increasing the efficiency of charge separation for the surface reaction. In this work, we have found different explanation.

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Preparation and Photocatalytic Performance of Anatase/Rutile Mixed ...

2010年8月13日  Abstract Anatase-dominated anatase/rutile mixed-phase TiO2 nanotubes were prepared by decorating TiO2 on the hydrothermally synthesized TiO2-derived nanotubes via liquid phase deposition and subsequent annealing. The morphology and structure of as-prepared TiO2 nanotubes were characterized by transmission electron

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